Toluene: Difference between revisions

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(Created page with "{{Compound|name=Toluene|chemf=C6H5CH3|mm=92.14|density=0.87|mp=-95|bp=111|nfpa_h=2|nfpa_f=3|stp_p=liquid|listed_dea=yes}} ==Uses== {{Justify}} ===Other=== * Solvent * General...")
 
 
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* Friedel-Crafts from [[benzene]] and [[chloromethane]] in an anhydrous environment over a catalyst from the list {{#Chem: AlCl3 > SbCl3 > SnCl4 > BF3 > ZnCl2 > HgCl2}}
* Friedel-Crafts from [[benzene]] and [[chloromethane]] in an anhydrous environment over a catalyst from the list {{#Chem: AlCl3 > SbCl3 > SnCl4 > BF3 > ZnCl2 > HgCl2}}
*: {{#Chem:  C6H6 + CH3Cl { AlCl3 = } C6H5CH3 + HCl}}
*: {{#Chem:  C6H6 + CH3Cl { AlCl3 = } C6H5CH3 + HCl}}
* From benzaldehyde
* From [[benzaldehyde]] via clemmensen reduction:
*: {{#Chem:C7H5OH {Zn, Hf, HCl = } C7H8 }}
* From phenol
* From phenol



Latest revision as of 18:19, 21 July 2021

Legality: DEA Listed Chemicals

Production of this substance may be illegal in some jurisdictions under certain circumstances.

21CFR1310.02 a & b

In 1995/6, two lists were created "List I" and "List II", for which commercial manufacturers and distributors must register, and for which possession with the intent to manufacture illegal substances (such as methamphetamine, ecstasy, etc) is illegal. On these a few dozen "precursor" compounds commonly used in the manufacture of illegal drugs. [1] [2]

Bottom line: Do not produce this chemical without checking to make sure that you may do so legally.

 
 
Toluene
DEA LIST I/II SUBSTANCE
Chemical formula C6H5CH3
OTP appearance liquid 
Molar Mass(g/mol) 92.14 
Density(g/cc) 0.87 
Melting Point(°C) -95 
Boiling Point(°C) 111
NFPA 704
NFPA704.png
3
2
0
 

Uses

Justification Questioned

Other

  • Solvent
  • General aromatic feedstock

Natural Occurrence

  • Does occur naturally in crude oil, naphtha, coal tar, etc.

Hazards

  • Flammable
  • Toxic

Production

Extraction

Synthesis

  • Friedel-Crafts from benzene and chloromethane in an anhydrous environment over a catalyst from the list AlCl3>SbCl3>SnCl4>BF3>ZnCl2>HgCl2
    C6H6 + CH3Cl
    {AlCl3
    }
    C6H5CH3 + HCl
  • From benzaldehyde via clemmensen reduction:
    C7H5OH
    {Zn,Hf,HCl
    }
    C7H8
  • From phenol

See Also

References

  1. "Emphasizing the "Control" in controlled substances"
    United States Drug Enforcement Agency
    link last accessed 11 September 2012.
  2. "Controlled Substances Act; Title 21; Chapter 13; Subchapter I"
    United States Food & Drug Administration
    link last accessed 11 September 2012.