Iron pyrite: Difference between revisions

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In contact with a wet natural environment (water, air, perhaps sunlight), pyrite weathers producing ferrous (and perhaps ferric) sulfates:
In contact with a wet natural environment (water, air, perhaps sunlight), pyrite weathers producing ferrous (and perhaps ferric) sulfates:
  {{#Chem: 4FeS2(s) + 14O2(g) + 4H2O(l)  =  4Fe<sup>II</sup> + 8SO4<sup>2-</sup> + 8H<sup>+</sup>}}
  {{#Chem: 4FeS2(s) + 14O2(g) + 4H2O(l)  =  4Fe<sup>II</sup> + 8SO4<sup>2-</sup> + 8H<sup>+</sup>}}
  {{#Chem: 4Fe<sup>II</sup> + O2 + 4H<sup>+</sup> =  4Fe<sup>III</sup> + 2H2O}}
  {{#Chem: 4Fe<sup>II</sup> + O2 + 2H2 =  4Fe<sup>III</sup> + 2H2O}}
  {{#Chem: 4Fe<sup>III</sup> + 12 H2O  =    4Fe(OH)3 + 12H<sup>+</sup>}}
  {{#Chem: 4Fe<sup>III</sup> + 12 H2O  =    4Fe(OH)3 + 12H<sup>+</sup>}}

Latest revision as of 18:32, 2 October 2019

Iron pyrite 
Frequency common 
Hardness 6-6.5 
Density 5
Chemical Formula {{#Chem:FeS2}} 
Core Elements Fe 
Thermal Decomposition
{{#Chem:FeS2}}
540-850°C
{{#Chem:Fe2O3}}

pyrite, along with Hematite and Magnetite is a primary ore of iron.

Weathering

In contact with a wet natural environment (water, air, perhaps sunlight), pyrite weathers producing ferrous (and perhaps ferric) sulfates:

{{#Chem: 4FeS2(s) + 14O2(g) + 4H2O(l)  =  4FeII + 8SO42- + 8H+}}
{{#Chem: 4FeII + O2 + 2H2  =   4FeIII + 2H2O}}
{{#Chem: 4FeIII + 12 H2O  =    4Fe(OH)3 + 12H+}}