Contact process
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The contact process is a process for producing sulfuric acid by passing a blend of sulfur dioxide and air over a solid catalyst, producing sulfur trioxide, which is then absorbed into water, producing sulfuric acid:
- Burn sulfur producing sulfur dioxide
- {{#Chem: S + O2 { = 983-1150°C } SO2 dH=-70.94}}
- Gas phase oxidation of sulfur dioxide ion air over a solid catalyst producing sulfur trioxide
- Absorb sulfur trioxide into sub-saturated sulfuric acid
- {{#Chem: SO3 + H2O {H2SO4 = } H2SO4 }}
Catalysts
Vanadium pentoxide
A mixture of 8% sulfur dioxide in air is passed over vanadium pentoxide producing sulfur trioxide
- {{#Chem: SO2 + ½O2 {V2O5=390-600°C, 1.2-1.4atm} SO3 dH=-23.64}}:
Platinum
- See also Platinum
- NB: Platinum catalysts can be rendered inert by gaseous arsenic in the feedstock gasses
- Soak asbestos, glass wool, quartz, or another inert substance in chloroplatinic acid
- Pyrolize the chloroplatinic acid, leaving finely divided platinum on the surface of the catalyst base
Pass a mixture of sulfur dioxide and air over the platinum catalyst
- {{#Chem: SO2 + ½O2 {Pt =} SO3}}