Solvay process

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The Solvay Process is a chemical process which uses ammonia to convert salt and calcium carbonate into sodium carbonate and calcium chloride.

  1. Roast calcium carbonate (Limestone) to give calcium oxide and carbon dioxide:
    CaCO3 CaO + CO2 // roast
  2. Bubble carbon dioxide through a mixture of aqueous ammonia and salt in water, giving ammonium chloride and sodium bicarbonate
    NaCl + NH3 + H2O + CO2 NaHCO3(s) + NH4Cl(aq)
  3. Filter off the sodium bicarbonate
  4. Recombine the calcium oxide with the aqueous ammonium chloride giving ammonia and calcium chloride.
    2 NH4Cl(aq) + CaO 2 NH3 + CaCl2 + H2O