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==Products==
{{#description2:Naturally Occurring Widely Available Chemical Library}}
* [[Video index|Videos]] are one of our primary products
==Goals==
* [[Library|Our chemical library]] lists the '''materials we've already produced'''.
# Produce  [[:Category:Library|a broad library]] of chemical materials which can be produced from [[:Category:NOWA|naturally occurring and widely available]] materials.
* [[:Category:NOWA|The NOWA category]] lists the materials we consider '''Naturally Occurring and Widely Available'''.
# Demonstrate the production of the chemicals in the library using '''only''' basic lab equipment
# Produce documentation of the processes demonstrated, primarily [[Video index|Videos]] and this wiki


==Goals==
==Upcoming Targets==
===Water===
===Water===
{| class="wikitable dtab"
Pure (ish) [[water]] is an essential for life,  not just chemistry. Preparing it at scale is important.
|+Water via distillation
!NOWA?
!Substance
!Status
|-
|{{nowatag}}||[[Salt water]]||'''Pending'''
|-
|{{libtag}}||[[Sea salt]]||'''Pending'''
|-
|{{libtag}}||[[Water|Distilled Water]]||'''Pending'''
|}
====Justification====
Pure (ish) water is an essential for life,  not just chemistry. Preparing it at scale is important.
====Path====
Distilling impure water gives a distillate with no dissolved solids or biological pathogens. There are compounds which form azeotropes with water, so the distillate may not be ''completely'' pure, but it will be adequate for our  purposes.
===A Natural Diversion===
{| class="wikitable dtab"
|+Ethanol, carbon dioxide, and acetic acid via monads
!NOWA?
!Substance
!Status
|-
|{{libtag}}||[[Water]]||'''Prev'''
|-
|{{nowatag}}||[[Honey]]||'''Pending'''
|-
|{{nowatag}}||[[Saccharomyces cerevisiae|Yeast]]||'''Pending'''
|-
|{{libtag}}||[[Ethanol]]||'''Pending'''
|-
|{{nowatag}}||[[Acetobacter]]||'''Pending'''
|-
|{{libtag}}||[[Acetic acid]]||'''Pending'''
|}
====Justification====
[[Ethanol]] and [[acetic acid]] are both produced as waste products by microbes. We will turn aside from our stream of logical goals to explore the principle of  "Let nature do the heavy lifting."
 
====Path====
* The production of ethanol and acetic acid  is still done the way we  do it here. There are other methods but we will follow the original path.  Natural yeasts produce [[ethanol]] from sugars, and acetobacter produce [[acetic acid]] from [[ethanol]]. Both yeasts and acetobacter are ubiquitous in our environment, and are easy to capture and culture. Both ethanol  and acetic acid are useful materials, and as a side benefit, yeasts produce [[carbon dioxide]] as a biproduct of producing ethanol. Nature is  willing to do a lot of chemistry for us if we'll just let her.
*: {{#Chem: C6H12O6 = 2C2H5OH + 2CO2 // yeast fermentation}}
*: {{#Chem: C2H5OH + O2  = CH3COOH + H2O  // acetobacter fermentation}}
 
===Calcium Hydroxide===
{| class="wikitable dtab"
|+Lye via lime
!NOWA?
!Substance
!Status
|-
|{{nowatag}}||[[Limestone]]||'''Pending'''
|-
|{{libtag}}||[[Calcium oxide]]||'''Pending'''
|-
|{{libtag}}||[[Calcium hydroxide]]||'''Pending'''
|}
====Justification====
Calcium hydroxide is a strong alkali and can be used to produce [[sodium hydroxide]].


====Path====
Distilling impure water gives a distillate with no dissolved solids or biological pathogens. There are compounds which form azeotropes with water, so the distillate may not be ''completely'' pure, but it will be adequate for most  purposes.
* Gather [[limestone]]
===Sodium Hydroxide===
* Heat it, producing calcium oxide.
An important industrial chemical, [[sodium hydroxide]] is an essential building block in chemistry. We will also produce [[calcium hydroxide]] as a side product.
* Slake it with water, producing calcium hydroxide.


===Ammonia===
===Ammonia===
{| class="wikitable dtab"
While [[ammonia]] is a major industrial chemical in itself, looking ahead to [[sulfuric acid]] production, ammonia is a required precursor to two of its catalysts, so it should come first.
|+Ammonia via urea hydrolysis
While the [[Haber process]] can indeed create ammonia from gaseous nitrogen, At first we will produce it from naturally occurring fixed nitrogen sources: [[keratin]] and [[urea]].
!NOWA?
!Substance
!Status
|-
|{{nowatag}}||[[Urine]]||'''Pending'''
|-
|{{libtag}}||[[Urea]]||'''Pending'''
|-
|{{libtag}}||[[Water|Distilled water]]||'''Prev'''
|-
|{{libtag}}||[[Sodium hydroxide]]||'''Prev'''
|-
|{{libtag}}||[[Ammonia]]||'''Pending'''
|}
====Justification====
[[Ammonia]] is an essential [[:Category:Industrial Chemicals|industrial chemical]]. It is the primary source of non-elemental [[nitrogen]]. Thus, producing some must be an early goal.
 
====Path====
* Currently, ammonia is mostly made by the [[Haber process]]. Unfortunately this requires  high temperatures, high pressures, and catalysts to work at anything more than a "droplets" scale,  definitely not  benchtop chemistry.
* It may be worth noting that the urine of some animals (fish and mice, for instance) is almost entirely ammonia, so collecting vast amounts of mouse urine is an alternative. We will not be exploring this.
* We will hydrolyze [[urea]] which is a naturally occurring component of the urine of most large animals, including humans. This we can do on a benchtop


===Sulfuric Acid===
===Sulfuric Acid===
{| class="wikitable dtab"
It can be argued that [[sulfuric acid]] is the '''primary''' [[:Category:Industrial Chemicals|industrial chemical]]. For the 19th and most of the 20th centuries, measuring a nation's sulfuric acid production was a good indicator of their degree of industrialization.
|+Sulfuric acid via copper chloride
====via catalysis====
!NOWA?
There are three catalytic ways to  produce [[sulfuric acid]] from [[sulfur dioxide]], They differ in the oxidation catalyst used, which can be chosen based on what materials are at hand.
!Substance
# '''Contact Process''' In 2020,  most industrially produced sulfuric acid is produced by the [[contact process]]. Unfortunately this requires catalysts made of somewhat rare materials, usually [[platinum]]  or [[vanadium pentoxide]]. It is also done at high temperatures. While this is not ''impossible'' on the benchtop, we will seek a more accessible way.
!Status
#  '''Copper Chloride''' Producing sulfuric acid via the [[copper chloride process]] requires  [[copper (II) chloride|copper chloride]]. Since copper chloride is not naturally occurring (except in very rare circumstances) we will first need to produce that, which will require [[ammonium chloride]] produced by the [[Solvay process]].
|-
# '''Nitrogen oxides''' Producing sulfuric acid via the [[chamber process]] requires [[nitric oxide]] (or [[nitric acid]]). Since neither of those is naturally occurring, they must be produced from [[ammonia]] via the [[Ostwald process]].
|{{libtag}}||[[Ammonia]]||'''Prev'''
|-
|{{libtag}}||[[Sea salt]]||'''Prev'''
|-
|{{nowatag}}||[[Carbon dioxide]]||'''Prev'''
|-
|{{libtag}}||[[Ammonium chloride]]||'''Pending'''
|-
|{{nowatag}}||[[chalcocite]]||'''Pending'''
|-
|{{libtag}}||[[copper (II) oxide]]||'''Pending'''
|-
|{{libtag}}||[[copper (II) chloride]]||'''Pending'''
|-
|{{libtag}}||[[sulfur dioxide]]||'''Pending'''
|-
|{{libtag}}||[[sulfuric acid]]||'''Pending'''
 
|}
====Justification====
It can be argued that [[sulfuric acid]] is ''the'' primary [[:Category:Industrial Chemicals|industrial chemical]]. For the 19th and most of the 20th centuries, measuring a nation's sulfuric acid production was a good indicator of their degree of industrialization.
 
====Path====
* Currently most sulfuric acid is produced by the [[contact process]]. Unfortunately this requires catalysts made of uncommonly rare materials, usually [[platinum]]  or [[vanadium pentoxide]]. It is also done at high temperatures. This is not impossible on the benchtop, but for now we will seek an easier way.
* We will produce sulfuric acid by the [[copper (II) chloride|copper chloride]] process. Since copper chloride is not naturally occurring (except in very rare circumstances) we will first need to produce that.
{{br}}
 
==Next Goal==
* [[Ethanol]]


==FAQ==
==FAQ==
# '''What is NOWA-CL?'''
# '''What is NOWA-CL?'''
#:There's a '''<span class=plainlinks>[https://www.youtube.com/watch?v=HB7SRhplEQM video]''' on that question.
#:NOWA stands for '''Naturally Occurring Widely Available'''. The CL stands for '''Chemical Library'''. This project is about documenting the technological steps involved in developing a library of chemical compounds that can be made with simple equipment from materials that are naturally occurring and widely available. There's no need to order chemicals from supply houses, or obtain them from over-the-counter products. Once a chemical has been produced in quantity from naturally occurring widely available sources, we add it to our "library". Then we can use that material to produce new materials. The important part is to demonstrate that they can be produced from these sources with minimal equipment: what the chemical industry refers to as "small-scale", "benchtop" or "laboratory" synthesis.<br/>The documentary part of this project will include two main products: the text on this wiki and the videos on YouTube.<br/>
#:
#:NOWA stands for '''Naturally Occurring Widely Available'''. The CL stands for '''Chemical Library'''. This project is about documenting the technological steps involved in developing a library of chemical compounds that can be made with simple equipment from materials that are naturally occurring and widely available. There's no need to order chemicals from supply houses, or obtain them from over-the-counter products. Once a chemical has been produced in quantity from naturally occurring widely available sources, we add it to our "library". Then we can use that material to produce new materials. The important part is to demonstrate that they can be produced from these sources with minimal equipment: what the chemical industry refers to as "small-scale" or "laboratory" synthesis.<br/>The documentary part of this project will include two main products: the text on this wiki and the videos on YouTube.<br/>
# '''So it's a recipe book where people can learn how to make chemicals?'''
# '''So it's a recipe book where people can learn how to make chemicals?'''
#: '''Definitely not.''' See [[Main_Page#WARNING|the warning on our front page]]. Chemistry ''equipment'' can be dangerous by itself. Many materials (including the ones we work with here) are dangerous: toxic, flammable, corrosive, etc. These operations <u>should not be repeated or reproduced</u> except by people who are sufficiently qualified to do the work and handle the materials safely.<br/>
#: '''Definitely not.''' See [[Main_Page#WARNING|the warning on our front page]]. Chemistry ''equipment'' can be dangerous by itself. Many materials (including the ones we work with here) are dangerous: toxic, flammable, corrosive, etc. These operations <u>should not be repeated or reproduced</u> except by people who are sufficiently qualified and equipped to do that work and handle the materials safely.<br/>
# '''Isn't there a kind of chicken-and-egg problem? What is your equipment made of?'''
# '''Isn't there a kind of chicken-and-egg problem? What is your equipment made of?'''
#: That's a good point. We assume that the equipment itself (glassware, supports, heat sources, etc) are available at the beginning. The equipment itself may not be naturally occurring, but it's widely available, accessible, and relatively cheap. The purpose of this project is to demonstrate that the ''process'' is the important part, not the chemicals you start with. It's the knowledge, not the resources, that enable the science.<br/>
#: That's a good point. We assume that the equipment itself (glassware, supports, heat sources, etc) are available at the beginning. The equipment itself may not be naturally occurring, but it's widely available, accessible, and relatively cheap. The purpose of this project is to demonstrate that the ''process'' is the important part, not the chemicals you start with. It's the knowledge, not the resources, that enable the science.<br/>
Line 146: Line 37:


=='''WARNING'''==
=='''WARNING'''==
<span style='font-size: 150%; font-weight:bold'>ANY</span> pursuit can be dangerous to the inexperienced, unprepared, or incautious. That is definitely the case with the reactions, extractions, and syntheses this project entails. Do not repeat them unless you are sufficiently informed, prepared, and equipped to handle these materials and safely do the work shown.
<div style="border:1px solid black;">
[[Image:danger.png|left]]
<span style='font-size: 150%; font-weight:bold'>ANY</span> pursuit can be dangerous to the unprepared, unequipped, or incautious. That is definitely the case with the reactions, extractions, and syntheses this project entails. Do not perform them unless you are sufficiently informed, prepared, equipped and cautious to handle these materials and safely do the work shown.
</div>


==Online==
==Find us online==
<div style="width:100%; text-align: center;">
<div style="width:100%; text-align: center;">
[[Image: yt.png|NOWA-CL at YouTube|link=https://www.youtube.com/channel/UCEQue5J94SQGFWpw0osw5qQ]]
[[Image: yt.png|NOWA-CL at YouTube|link=https://www.youtube.com/channel/UCEQue5J94SQGFWpw0osw5qQ]]
[[Image: fb.png|NOWA-CL at Facebook|link=https://www.facebook.com/Nowa-cl-193477368273685/]]
[[Image: patreon.png|NOWA-CL at Patreon|link=https://patreon.com/nowacl]]
[[Image: patreon.png|NOWA-CL at Patreon|link=https://patreon.com/nowacl]]
</div>
</div>
<hr/><div style=' widrh: 100%; text-align: center; font-weigh: bold;'>[[Main Page|Home]] [[Video index]]</div>
<hr/><div style=' widrh: 100%; text-align: center; font-weigh: bold;'>[[Main Page|Home]] [[Video index]]</div>

Latest revision as of 16:01, 29 March 2025

{{#description2:Naturally Occurring Widely Available Chemical Library}}

Goals

  1. Produce a broad library of chemical materials which can be produced from naturally occurring and widely available materials.
  2. Demonstrate the production of the chemicals in the library using only basic lab equipment
  3. Produce documentation of the processes demonstrated, primarily Videos and this wiki

Upcoming Targets

Water

Pure (ish) water is an essential for life, not just chemistry. Preparing it at scale is important.

Distilling impure water gives a distillate with no dissolved solids or biological pathogens. There are compounds which form azeotropes with water, so the distillate may not be completely pure, but it will be adequate for most purposes.

Sodium Hydroxide

An important industrial chemical, sodium hydroxide is an essential building block in chemistry. We will also produce calcium hydroxide as a side product.

Ammonia

While ammonia is a major industrial chemical in itself, looking ahead to sulfuric acid production, ammonia is a required precursor to two of its catalysts, so it should come first. While the Haber process can indeed create ammonia from gaseous nitrogen, At first we will produce it from naturally occurring fixed nitrogen sources: keratin and urea.

Sulfuric Acid

It can be argued that sulfuric acid is the primary industrial chemical. For the 19th and most of the 20th centuries, measuring a nation's sulfuric acid production was a good indicator of their degree of industrialization.

via catalysis

There are three catalytic ways to produce sulfuric acid from sulfur dioxide, They differ in the oxidation catalyst used, which can be chosen based on what materials are at hand.

  1. Contact Process In 2020, most industrially produced sulfuric acid is produced by the contact process. Unfortunately this requires catalysts made of somewhat rare materials, usually platinum or vanadium pentoxide. It is also done at high temperatures. While this is not impossible on the benchtop, we will seek a more accessible way.
  2. Copper Chloride Producing sulfuric acid via the copper chloride process requires copper chloride. Since copper chloride is not naturally occurring (except in very rare circumstances) we will first need to produce that, which will require ammonium chloride produced by the Solvay process.
  3. Nitrogen oxides Producing sulfuric acid via the chamber process requires nitric oxide (or nitric acid). Since neither of those is naturally occurring, they must be produced from ammonia via the Ostwald process.

FAQ

  1. What is NOWA-CL?
    NOWA stands for Naturally Occurring Widely Available. The CL stands for Chemical Library. This project is about documenting the technological steps involved in developing a library of chemical compounds that can be made with simple equipment from materials that are naturally occurring and widely available. There's no need to order chemicals from supply houses, or obtain them from over-the-counter products. Once a chemical has been produced in quantity from naturally occurring widely available sources, we add it to our "library". Then we can use that material to produce new materials. The important part is to demonstrate that they can be produced from these sources with minimal equipment: what the chemical industry refers to as "small-scale", "benchtop" or "laboratory" synthesis.
    The documentary part of this project will include two main products: the text on this wiki and the videos on YouTube.
  2. So it's a recipe book where people can learn how to make chemicals?
    Definitely not. See the warning on our front page. Chemistry equipment can be dangerous by itself. Many materials (including the ones we work with here) are dangerous: toxic, flammable, corrosive, etc. These operations should not be repeated or reproduced except by people who are sufficiently qualified and equipped to do that work and handle the materials safely.
  3. Isn't there a kind of chicken-and-egg problem? What is your equipment made of?
    That's a good point. We assume that the equipment itself (glassware, supports, heat sources, etc) are available at the beginning. The equipment itself may not be naturally occurring, but it's widely available, accessible, and relatively cheap. The purpose of this project is to demonstrate that the process is the important part, not the chemicals you start with. It's the knowledge, not the resources, that enable the science.
  4. There are already too many wikis out there. Why start a new one? (aka Why not just put this information in Wikipedia?)
    1. Aggregating and disseminating this information was the purpose of this project, and wikis are an excellent way to do both of those things, so that part is straightforward.
    2. Wikipedia is specifically not a textbook, guidebook, or instruction manual. That means it isn't appropriate to build out those entries with much of the data in this wiki. To whatever degree it makes sense for both projects, sharing of data is welcomed and encouraged. NB: A lot of the numeric data in this wiki comes directly from either Wikipedia or its underlying sources.

WARNING

ANY pursuit can be dangerous to the unprepared, unequipped, or incautious. That is definitely the case with the reactions, extractions, and syntheses this project entails. Do not perform them unless you are sufficiently informed, prepared, equipped and cautious to handle these materials and safely do the work shown.

Find us online

NOWA-CL at YouTube NOWA-CL at Patreon


Home Video index